Online teaching and learning process has become new normal and being adopted by many higher learning organizations throughout the globe at the present scenario. Despite of the fact that online methodology is not being a new approach, major contribution of this process is confined in recent past to special learning aspects like certification programs, training programs in many countries. However, in present scenario, online teaching learning is playing very important roleas it has been well recognized throughout the globeas one of the better facilitation approaches of education and degrees.  The salient implementation includes the academic processes with minimal time lapse and knowledge loss for the learning fraternity and hence become best option for possible best compensation in particular working professionals. Though this approach is very attractive, there is a greater need to address several issues most likely to identify during the online teaching learning process. One of the biggest needs in this regard is to avoid demotivation of learners and to enhance their positive learning skills so as to synergize the mentoring system in present online teaching and learning process as in the case of conventional practices. With a prior experience of authors in the assessment in online education, the present study is an attempt of proposed and preferable analysis of online global wide national mentoring approach which supports teaching faculty of different expertise includes fresh, moderate and senior faculty members acting as mentors in online teaching at demographically distant renowned Universities. The authors identified some reputed Universities (12 No.s) found active in online teaching learning process for survey, collection of required information and necessary discussions for better efficacy. Survey data with enthusiastic teachers from various selected Universities in India and other countries analyzed by using an interactive analysis approach to describe how the restructured mentoring system in online teaching and learning process can be utilized by teaching fraternity and to effectively implement for their concerned learners and courses. This synergized mentoring approach will have huge positive impact on the mentees to achieve their GOAL (Going Online As Learners). Besides this significant implication, the specific dimension of how physical distance impact mentors authenticity in mentoring has also been identified in the study.